When a molecule absorbs a particular frequency and changes electron distribution, vibrates, or rotates, it will eventually relax. When it relaxes, it will release the energy it absorbed in the form of electromagnetic radiation. Due to this, we can still use absorption and emission spectra to identify the presence of particular molecules.
Electromagnetic Radiation | Electromagnetic Frequency | Light | Generating Electromagnetic Radiation | Sources of Electromagnetic Radiation | Reflection and Absorption | Atomic Spectroscopy | Molecular Spectrscopy